uni-leipzig-open-access/json/s43246-023-00349-4

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Here, we report on defect engineering of silicon with ion pulses from a laser accelerator in the laser intensity range of 10<jats:sup>19<\/jats:sup>\u2009W\u2009cm<jats:sup>\u22122<\/jats:sup> and ion flux levels of up to 10<jats:sup>22<\/jats:sup>\u2009ions\u2009cm<jats:sup>\u22122<\/jats:sup> s<jats:sup>\u22121<\/jats:sup>, about five orders of magnitude higher than conventional ion implanters. Low energy ions from plasma expansion of the laser-foil target are implanted near the surface and then diffuse into silicon samples locally pre-heated by high energy ions from the same laser-ion pulse. Silicon crystals exfoliate in the areas of highest energy deposition. Color centers, predominantly W and G-centers, form directly in response to ion pulses without a subsequent annealing step. We find that the linewidth of G-centers increases with high ion flux faster than the linewidth of W-centers, consistent with density functional theory calculations of their electronic structure. Intense ion pulses from a laser-accelerator drive materials far from equilibrium and enable direct local defect engineering and high flux doping of semiconductors.<\/jats:p>","DOI":"10.1038\/s43246-023-00349-4","type":"journal-article","created":{"date-parts":[[2023,3,27]],"date-time":"2023-03-27T19:03:30Z","timestamp":1679943810000},"update-policy":"http:\/\/dx.doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Defect engineering of silicon with ion pulses from laser acceleration"],"prefix":"10.1038","volume":"4","author":[{"given":"Walid","family":"Redjem","sequence":"first","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-3433-2698","authenticated-orcid":false,"given":"Ariel J.","family":"Amsellem","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-0311-8624","authenticated-orcid":false,"given":"Frances I.","family":"Allen","sequence":"additional","affiliation":[]},{"given":"Gabriele","family":"Benndorf","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6381-1394","authenticated-orcid":false,"given":"Jianhui","family":"Bin","sequence":"additional","affiliation":[]},{"given":"Stepan","family":"Bulanov","sequence":"additional","affiliation":[]},{"given":"Eric","family":"Esarey","sequence":"additional","affiliation":[]},{"given":"Leonard C.","family":"Feldman","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-1840-2553","authenticated-orcid":false,"given":"Javier","family":"Ferrer Fernandez","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4107-4383","authenticated-orcid":false,"given":"Javier","family":"Garcia Lopez","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-3276-8781","authenticated-orcid":false,"given":"Laura","family":"Geulig","sequence":"additional","affiliation":[]},{"given":"Cameron R.","family":"Geddes","sequence":"additional","affiliation":[]},{"given":"Hussein","family":"Hijazi","sequence":"additional","affiliation":[]},{"given":"Qing","family":"Ji","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-7285-2603","authenticated-orcid":false,"given":"Vsevolod","family":"Ivanov","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-5633-4163","authenticated-orcid":false,"given":"Boubacar","family":"Kant\u00e9","sequence":"additional","affiliation":[]},{"given":"Anthony","family":"Gonsalves","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-6689-1219","authenticated-orcid":false,"given":"Jan","family":"Meijer","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-9842-7114","authenticated-orcid":false,"given":"Kei","family":"Nakamura","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-3186-8358","authenticated-orcid":false,"given":"Arun","family":"Persaud","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-8996-4249","authenticated-orcid":false,"given":"Ian","family":"Pong","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-9236-8037","authenticated-orcid":false,"given":"Lieselotte","family":"Obst-Huebl","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6925-3995","authenticated-orcid":false,"given":"Peter A.","family":"Seidl","sequence":"additional","affiliation":[]},{"given":"Jacopo","family":"Simoni","sequence":"additional","affiliation":[]},{"given":"Carl","family":"Schroeder","sequence":"additional","affiliation":[]},{"given":"Sven","family":"Steinke","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4724-6369","authenticated-orcid":false,"given":"Liang Z.","family":"Tan","sequence":"additional","affiliation":[]},{"given":"Ralf","family":"Wunderlich","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-0593-2195","authenticated-orcid":false,"given":"Brian","family":"Wynne","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4046-9252","authenticated-orcid":false,"given":"Thomas","family":"Schenkel","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2023,3,27]]},"reference":[{"key":"349_CR1","unstructured":"Chang, C. 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