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Here we present global CCN measurements, covering diverse environments from pristine to highly polluted conditions. We show that the effective aerosol hygroscopicity,<jats:italic>\u03ba<\/jats:italic>, can be derived accurately from the fine aerosol mass fractions of organic particulate matter (<jats:italic>\u03f5<\/jats:italic><jats:sub>org<\/jats:sub>) and inorganic ions (<jats:italic>\u03f5<\/jats:italic><jats:sub>inorg<\/jats:sub>) through a linear combination,<jats:italic>\u03ba<\/jats:italic>\u2009=\u2009<jats:italic>\u03f5<\/jats:italic><jats:sub>org<\/jats:sub>\u2009\u22c5\u2009<jats:italic>\u03ba<\/jats:italic><jats:sub>org<\/jats:sub>\u2009+\u2009<jats:italic>\u03f5<\/jats:italic><jats:sub>inorg<\/jats:sub>\u2009\u22c5\u2009<jats:italic>\u03ba<\/jats:italic><jats:sub>inorg<\/jats:sub>. In spite of the chemical complexity of organic matter, its hygroscopicity is well captured and represented by a global average value of<jats:italic>\u03ba<\/jats:italic><jats:sub>org<\/jats:sub>\u2009=\u20090.12\u2009\u00b1\u20090.02 with<jats:italic>\u03ba<\/jats:italic><jats:sub>inorg<\/jats:sub>\u2009=\u20090.63\u2009\u00b1\u20090.01 as the corresponding value for inorganic ions. By showing that the sensitivity of global climate forcing to changes in<jats:italic>\u03ba<\/jats:italic><jats:sub>org<\/jats:sub>and<jats:italic>\u03ba<\/jats:italic><jats:sub>inorg<\/jats:sub>is small, we constrain a critically important aspect of global climate modelling.<\/jats:p>","DOI":"10.1038\/s41467-023-41695-8","type":"journal-article","created":{"date-parts":[[2023,10,2]],"date-time":"2023-10-02T10:02:21Z","timestamp":1696240941000},"update-policy":"http:\/\/dx.doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Global organic and inorganic aerosol hygroscopicity and its effect on radiative forcing"],"prefix":"10.1038","volume":"14","author":[{"ORCID":"http:\/\/orcid.org\/0000-0001-6852-0756","authenticated-orcid":false,"given":"Mira L.","family":"P\u00f6hlker","sequence":"first","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6958-425X","authenticated-orcid":false,"given":"Christopher","family":"P\u00f6hlker","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7057-194X","authenticated-orcid":false,"given":"Johannes","family":"Quaas","sequence":"additional","affiliation":[]},{"given":"Johannes","family":"M\u00fclmenst\u00e4dt","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-2440-6104","authenticated-orcid":false,"given":"Andrea","family":"Pozzer","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-1968-7925","authenticated-orcid":false,"given":"Meinrat O.","family":"Andreae","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7754-3036","authenticated-orcid":false,"given":"Paulo","family":"Artaxo","sequence":"additional","affiliation":[]},{"given":"Karoline","family":"Block","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-3264-1713","authenticated-orcid":false,"given":"Hugh","family":"Coe","sequence":"additional","affiliation":[]},{"given":"Barbara","family":"Ervens","sequence":"additional","affiliation":[]},{"given":"Peter","family":"Gallimore","sequence":"additional","affiliation":[]},{"given":"Cassandra J.","family":"Gaston","sequence":"additional","affiliation":[]},{"given":"Sachin S.","family":"Gunthe","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-9267-7825","authenticated-orcid":false,"given":"Silvia","family":"Henning","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7044-2101","authenticated-orcid":false,"given":"Hartmut","family":"Herrmann","sequence":"additional","affiliation":[]},{"given":"Ovid O.","family":"Kr\u00fcger","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-3423-7896","authenticated-orcid":false,"given":"Gordon","family":"McFiggans","sequence":"additional","affiliation":[]},{"given":"Laurent","family":"Poulain","sequence":"additional","affiliation":[]},{"given":"Subha S.","family":"Raj","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4710-2277","authenticated-orcid":false,"given":"Ernesto","family":"Reyes-Villegas","sequence":"additional","affiliation":[]},{"given":"Haley M.","family":"Royer","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6807-5007","authenticated-orcid":false,"given":"David","family":"Walter","sequence":"additional","affiliation":[]},{"given":"Yuan","family":"Wang","sequence":"additional","affiliation":[]},{"given":"Ulrich","family":"P\u00f6schl","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2023,10,2]]},"reference":[{"key":"41695_CR1","doi-asserted-by":"crossref","unstructured":"Forster, P. et al. 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