1 line
27 KiB
Plaintext
1 line
27 KiB
Plaintext
{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,1,18]],"date-time":"2024-01-18T11:39:49Z","timestamp":1705577989424},"reference-count":78,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2023,3,12]],"date-time":"2023-03-12T00:00:00Z","timestamp":1678579200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Studienstiftung des deutschen Volkes"},{"name":"Graduate School BuildMoNa"},{"name":"National Research, Development and Innovation Office","award":["OTKA-FK 138823"]},{"name":"J\u00e1nos Bolyai Research Scholarship of the Hungarian Academy of Sciences"},{"name":"\u00daNKP-22-5 New National Excellence Program from the National Research, Development and Innovation Fund"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Two heterobimetallic Mo,M\u2019 complexes (M\u2019 = IrIII, RhIII) were synthesized and fully characterized. Their catalytic activity in homogeneous carbon dioxide hydrogenation to formate was studied. A pronounced synergistic effect between the two metals was found, most notably between Mo and Ir, leading to a fourfold increase in activity compared with a binary mixture of the two monometallic counterparts. This synergism can be attributed to spatial proximity of the two metals rather than electronic interactions. To further understand the nature of this interaction, the mechanism of the CO2 hydrogenation to formate by a monometallic IrIII catalyst was studied using computational and spectroscopic methods. The resting state of the reaction was found to be the metal-base adduct, whereas the rate-determining step is the inner-sphere hydride transfer to CO2. Based on these findings, the synergism in the heterobimetallic complex is beneficial in this key step, most likely by further activating the CO2.<\/jats:p>","DOI":"10.3390\/molecules28062574","type":"journal-article","created":{"date-parts":[[2023,3,13]],"date-time":"2023-03-13T07:28:33Z","timestamp":1678692513000},"page":"2574","source":"Crossref","is-referenced-by-count":4,"title":["Synergistic Catalysis in Heterobimetallic Complexes for Homogeneous Carbon Dioxide Hydrogenation"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"http:\/\/orcid.org\/0000-0001-5983-1288","authenticated-orcid":false,"given":"Zeno B. G.","family":"Fickenscher","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry, Universit\u00e4t Leipzig, Johannisallee 29, 04103 Leipzig, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-1335-0897","authenticated-orcid":false,"given":"Peter","family":"L\u00f6nnecke","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry, Universit\u00e4t Leipzig, Johannisallee 29, 04103 Leipzig, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6406-5450","authenticated-orcid":false,"given":"Anna K.","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Mulliken Center for Theoretical Chemistry, Institute for Physical and Theoretical Chemistry, Beringstr. 4, 53115 Bonn, Germany"}]},{"given":"Oldamur","family":"Holl\u00f3czki","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, Faculty of Science and Technology, University of Debrecen, Egyetem ter 1, H-4010 Debrecen, Hungary"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-8843-7132","authenticated-orcid":false,"given":"Barbara","family":"Kirchner","sequence":"additional","affiliation":[{"name":"Mulliken Center for Theoretical Chemistry, Institute for Physical and Theoretical Chemistry, Beringstr. 4, 53115 Bonn, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4267-0603","authenticated-orcid":false,"given":"Evamarie","family":"Hey-Hawkins","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry, Universit\u00e4t Leipzig, Johannisallee 29, 04103 Leipzig, Germany"}]}],"member":"1968","published-online":{"date-parts":[[2023,3,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"472","DOI":"10.1038\/461472a","article-title":"A safe operating space for humanity","volume":"461","author":"Steffen","year":"2009","journal-title":"Nature"},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Beller, M., and Bolm, C. (2004). Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals, Wiley VCH. [2nd ed.].","DOI":"10.1002\/9783527619405"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"2339","DOI":"10.1002\/anie.199623391","article-title":"Asymmetric Two-Center Catalysis\u2014Learning from Nature","volume":"35","author":"Steinhagen","year":"1996","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"2489","DOI":"10.1002\/ange.19961082005","article-title":"Asymmetrische Zweizentren-Katalyse\u2014Von der Natur lernen","volume":"108","author":"Steinhagen","year":"1996","journal-title":"Angew. Chem."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"6621","DOI":"10.1021\/cr300463y","article-title":"Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation","volume":"113","author":"Appel","year":"2013","journal-title":"Chem. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"4149","DOI":"10.1021\/cr400461p","article-title":"Structure, function, and mechanism of the nickel metalloenzymes, CO dehydrogenase, and acetyl-CoA synthase","volume":"114","author":"Can","year":"2014","journal-title":"Chem. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1021\/cr500208k","article-title":"Multimetallic catalysis based on heterometallic complexes and clusters","volume":"115","author":"Buchwalter","year":"2015","journal-title":"Chem. Rev."},{"key":"ref_8","first-page":"170","article-title":"Heterobimetallic Complexes as Promising Catalysts","volume":"5","author":"Chaudhary","year":"2016","journal-title":"Chem. Sci. Rev. Lett."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/01614940.2012.619931","article-title":"Catalytic Applications of Early\/Late Heterobimetallic Complexes","volume":"54","author":"Cooper","year":"2012","journal-title":"Catal. Rev."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Kalck, P. (2016). Homo-and Heterobimetallic Complexes in Catalysis, Springer International Publishing.","DOI":"10.1007\/978-3-319-34184-2"},{"key":"ref_11","unstructured":"Moret, M.-E., and Gebbink, R.J.M. (2019). Non-Noble Metal Catalysis: Molecular Approaches and Reactions, Wiley-VCH."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"10664","DOI":"10.1039\/c3dt50963j","article-title":"Polymetallic complexes linked to a single-frame ligand: Cooperative effects in catalysis","volume":"42","author":"Bratko","year":"2013","journal-title":"Dalton Trans."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1723","DOI":"10.1039\/C3SC53126K","article-title":"Heterometallic complexes, tandem catalysis and catalytic cooperativity","volume":"5","author":"Mata","year":"2014","journal-title":"Chem. Sci."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"222","DOI":"10.1016\/j.jcat.2016.02.031","article-title":"Tandem Suzuki\u2013Miyaura\/transfer hydrogenation reaction catalyzed by a Pd\u2013Ru complex bearing an anionic dicarbene","volume":"338","author":"Bitzer","year":"2016","journal-title":"J. Catal."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1576","DOI":"10.1039\/c0dt01211d","article-title":"Heterobimetallic complexes containing an N-heterocyclic carbene based multidentate ligand and catalyzed tandem click\/Sonogashira reactions","volume":"40","author":"Gu","year":"2011","journal-title":"Dalton Trans."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"6450","DOI":"10.1021\/om300675p","article-title":"Heterobimetallic Iridium\u2013Ruthenium Assemblies through an Ambidentate Triazole-Diylidene Ligand: Electrochemical Properties and Catalytic Behavior in a Cascade Reaction","volume":"31","author":"Sabater","year":"2012","journal-title":"Organometallics"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1508","DOI":"10.1021\/jacs.7b12174","article-title":"Stereodivergent Synthesis of \u03b1,\u03b1-Disubstituted \u03b1-Amino Acids via Synergistic Cu\/Ir Catalysis","volume":"140","author":"Wei","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"14531","DOI":"10.1021\/ja906028g","article-title":"Well-defined Ir\/Pd complexes with a triazolyl-diylidene bridge as catalysts for multiple tandem reactions","volume":"131","author":"Zanardi","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"13109","DOI":"10.1002\/chem.201001180","article-title":"An Ir-Pt catalyst for the multistep preparation of functionalized indoles from the reaction of amino alcohols and alkynyl alcohols","volume":"16","author":"Zanardi","year":"2010","journal-title":"Chemistry"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"12042","DOI":"10.1021\/acs.inorgchem.6b02223","article-title":"Solvent-Dependent Thermochemistry of an Iridium\/Ruthenium H2 Evolution Catalyst","volume":"55","author":"Brereton","year":"2016","journal-title":"Inorg. Chem."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"15078","DOI":"10.1021\/jacs.5b09913","article-title":"Greater than the Sum of Its Parts: A Heterodinuclear Polymerization Catalyst","volume":"137","author":"Garden","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"4618","DOI":"10.1039\/C9SC00385A","article-title":"Heterodinuclear zinc and magnesium catalysts for epoxide\/CO2 ring opening copolymerizations","volume":"10","author":"Trott","year":"2019","journal-title":"Chem. Sci."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"15575","DOI":"10.1021\/acs.inorgchem.8b02923","article-title":"Groups 1, 2 and Zn(II) Heterodinuclear Catalysts for Epoxide\/CO2 Ring-Opening Copolymerization","volume":"57","author":"Deacy","year":"2018","journal-title":"Inorg. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"11976","DOI":"10.1021\/acs.inorgchem.0c00812","article-title":"Cooperative Effects of Heterodinuclear IrIII-MII Complexes on Catalytic H2 Evolution from Formic Acid Dehydrogenation in Water","volume":"59","author":"Hong","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"863","DOI":"10.1246\/cl.1976.863","article-title":"Catalytic Fixation of Carbon Dioxide to Formic Acid by Transition-Metal Complexes under Mild Conditions","volume":"5","author":"Inoue","year":"1976","journal-title":"Chem. Lett."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1016\/j.jpowsour.2008.03.075","article-title":"Recent advances in direct formic acid fuel cells (DFAFC)","volume":"182","author":"Yu","year":"2008","journal-title":"J. Power Sources"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"7296","DOI":"10.1002\/anie.201507458","article-title":"Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry","volume":"55","author":"Klankermayer","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"7416","DOI":"10.1002\/ange.201507458","article-title":"Selektive katalytische Synthesen mit Kohlendioxid und Wasserstoff: Katalyse-Schach an der Nahtstelle zwischen Energie und Chemie","volume":"128","author":"Klankermayer","year":"2016","journal-title":"Angew. Chem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1007\/s41061-017-0107-x","article-title":"Homogeneous Reduction of Carbon Dioxide with Hydrogen","volume":"375","author":"Dong","year":"2017","journal-title":"Top. Curr. Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"12936","DOI":"10.1021\/acs.chemrev.5b00197","article-title":"CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction","volume":"115","author":"Wang","year":"2015","journal-title":"Chem. Rev."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"14244","DOI":"10.1021\/jacs.7b07911","article-title":"A Bimetallic Nickel-Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride","volume":"139","author":"Cammarota","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"4955","DOI":"10.1021\/acscatal.8b00803","article-title":"Rationalizing the Reactivity of Bimetallic Molecular Catalysts for CO2 Hydrogenation","volume":"8","author":"Ye","year":"2018","journal-title":"ACS Catal."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"2459","DOI":"10.1021\/acscatal.9b03534","article-title":"Cobalt-Group 13 Complexes Catalyze CO2 Hydrogenation via a Co(\u2212I)\/Co(I) Redox Cycle","volume":"10","author":"Vollmer","year":"2020","journal-title":"ACS Catal."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"6735","DOI":"10.1002\/ejoc.201900956","article-title":"On the Basicity of Organic Bases in Different Media","volume":"2019","author":"Tshepelevitsh","year":"2019","journal-title":"Eur. J. Org. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"627","DOI":"10.1246\/cl.190180","article-title":"Thermodynamic Cycles Relevant to Hydrogenation of CO2 to Formic Acid in Water and Acetonitrile","volume":"48","author":"Matsubara","year":"2019","journal-title":"Chem. Lett."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"11279","DOI":"10.1021\/acs.jpcb.6b08561","article-title":"A Reinvestigation of the Ionic Liquid Diisopropylethylammonium Formate by NMR and DFT Methods","volume":"120","author":"Hansen","year":"2016","journal-title":"J. Phys Chem. B"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"1452","DOI":"10.1039\/C4CY01233J","article-title":"Efficient hydrosilylation of imines using catalysts based on iridium(III) metallacycles","volume":"5","author":"Corre","year":"2015","journal-title":"Catal. Sci. Technol."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"4864","DOI":"10.1021\/acs.organomet.7b00749","article-title":"Iridacycles as Catalysts for the Autotandem Conversion of Nitriles into Amines by Hydrosilylation: Experimental Investigation and Scope","volume":"36","author":"Hamdaoui","year":"2017","journal-title":"Organometallics"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"11284","DOI":"10.1021\/acs.inorgchem.9b02104","article-title":"Mechanistic Insight into Synergistic Catalysis of Olefin Hydrogenation by a Hetero-Dinuclear RuII-CoII Complex with Adjacent Reaction Sites","volume":"58","author":"Hong","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"12985","DOI":"10.1016\/S0040-4020(98)00319-6","article-title":"Bimetallic catalysis by late transition metal complexes","volume":"54","author":"Feringa","year":"1998","journal-title":"Tetrahedron"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"17900","DOI":"10.1021\/jacs.9b09540","article-title":"Hydrogenation of N-Heteroarenes Using Rhodium Precatalysts: Reductive Elimination Leads to Formation of Multimetallic Clusters","volume":"141","author":"Kim","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"5938","DOI":"10.1021\/ja412309j","article-title":"Kinetics and thermodynamics of H-\/H\u2022\/H+ transfer from a rhodium(III) hydride","volume":"136","author":"Hu","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"Huber, K.-P., and Herzberg, G. (1979). Molecular Spectra and Molecular Structure: IV. Constants of Diatomic Molecules, Springer. Springer US; Imprint.","DOI":"10.1007\/978-1-4757-0961-2_2"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"860","DOI":"10.1002\/1099-0739(200012)14:12<860::AID-AOC87>3.0.CO;2-A","article-title":"Hydricity of transition-metal hydrides and its role in CO2 reduction","volume":"14","author":"DuBois","year":"2000","journal-title":"Appl. Organometal. Chem."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"5058","DOI":"10.1021\/om300398r","article-title":"Synthesis, Electrochemistry, and Reactivity of New Iridium(III) and Rhodium(III) Hydrides","volume":"31","author":"Hu","year":"2012","journal-title":"Organometallics"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1039\/tf9383400011","article-title":"Inertia and driving force of chemical reactions","volume":"34","author":"Evans","year":"1938","journal-title":"Trans. Faraday Soc."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"2286","DOI":"10.1021\/ja00269a026","article-title":"Carbon dioxide chemistry. Synthesis, properties, and structural characterization of stable bis(carbon dioxide) adducts of molybdenum","volume":"108","author":"Alvarez","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"520","DOI":"10.1021\/om100891m","article-title":"Kinetics and Mechanism of Molybdenum-Mediated Acrylate Formation from Carbon Dioxide and Ethylene","volume":"30","author":"Bernskoetter","year":"2011","journal-title":"Organometallics"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"1337","DOI":"10.1021\/om00118a077","article-title":"Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands","volume":"9","author":"Carmona","year":"1990","journal-title":"Organometallics"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"3425","DOI":"10.1021\/om500324h","article-title":"Ancillary Ligand Effects on Carbon Dioxide-Ethylene Coupling at Zerovalent Molybdenum","volume":"33","author":"Hanna","year":"2014","journal-title":"Organometallics"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"3969","DOI":"10.1021\/om400448m","article-title":"Functionalization of Carbon Dioxide with Ethylene at Molybdenum Hydride Complexes","volume":"32","author":"Zhang","year":"2013","journal-title":"Organometallics"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"C35","DOI":"10.1016\/0022-328X(92)83136-6","article-title":"Photochemistry of (Me3P)4Mo(\u03b7-CO2)2: Deoxygenation of coordinated carbon dioxide and phosphine oxidation","volume":"423","author":"Ziegler","year":"1992","journal-title":"J. Organomet. Chem."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1002\/wcms.81","article-title":"The ORCA program system","volume":"2","author":"Neese","year":"2012","journal-title":"WIREs Comput. Mol. Sci."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"3098","DOI":"10.1103\/PhysRevA.38.3098","article-title":"Density-functional exchange-energy approximation with correct asymptotic behavior","volume":"38","author":"Becke","year":"1988","journal-title":"Phys. Rev. A Gen. Phys."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","article-title":"Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density","volume":"37","author":"Lee","year":"1988","journal-title":"Phys. Rev. B Condens. Matter"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","article-title":"Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"1456","DOI":"10.1002\/jcc.21759","article-title":"Effect of the damping function in dispersion corrected density functional theory","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","article-title":"A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"1995","DOI":"10.1021\/jp9716997","article-title":"Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model","volume":"102","author":"Barone","year":"1998","journal-title":"J. Phys. Chem. A"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1080\/03086648108078285","article-title":"Nouveaux ylures du phosphore a partir e tris(amino)iminophosphanes et d\u2019esters acetyleniques. etude structurale par RMN de 13C","volume":"12","author":"Bellan","year":"1981","journal-title":"Phosphorus Sulfur Silicon Relat. Elem."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"6921","DOI":"10.1002\/anie.201703244","article-title":"N2 -to-NH3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis","volume":"56","author":"Buscagan","year":"2017","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"16032","DOI":"10.1021\/ja056071l","article-title":"Structural snapshots of a flexible Cu2P2 core that accommodates the oxidation states CuICuI, Cu1.5Cu1.5, and CuIICuII","volume":"127","author":"Mankad","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"3492","DOI":"10.1021\/om9000742","article-title":"C\u2212H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism","volume":"28","author":"Li","year":"2009","journal-title":"Organometallics"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"5970","DOI":"10.1021\/ja01050a008","article-title":"Pentamethylcyclopentadienylrhodium and -iridium halides. I. Synthesis and properties","volume":"91","author":"Kang","year":"1969","journal-title":"J. Am. Chem. Soc."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"326","DOI":"10.1002\/cmr.10035","article-title":"NMR nomenclature: Nuclear spin properties and conventions for chemical shifts (IUPAC recommendations 2001)","volume":"14","author":"Harris","year":"2002","journal-title":"Concepts Magn. Reson."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"887","DOI":"10.1107\/S0108767395007367","article-title":"The analytical calculation of absorption in multifaceted crystals","volume":"51","author":"Clark","year":"1995","journal-title":"Acta. Crystallogr. A"},{"key":"ref_67","unstructured":"Rigaku Oxford Diffraction (2023, February 17). CrysAlisPro Software Systems, Rigaku Corporation, Oxford, UK 201-2020. Available online: https:\/\/www.rigaku.com\/products\/crystallography\/crysalis."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT - integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta. Crystallogr. A"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"461","DOI":"10.1351\/pac198456040461","article-title":"Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983)","volume":"56","author":"Gritzner","year":"1984","journal-title":"Pure Appl. Chem."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"6713","DOI":"10.1021\/jp991381+","article-title":"The Decamethylferrocenium\/Decamethylferrocene Redox Couple: A Superior Redox Standard to the Ferrocenium\/Ferrocene Redox Couple for Studying Solvent Effects on the Thermodynamics of Electron Transfer","volume":"103","author":"Noviandri","year":"1999","journal-title":"J Phys Chem B"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1016\/S0022-328X(97)00143-5","article-title":"Titration of alkyllithiums with a simple reagent to a blue endpoint","volume":"542","author":"Burchat","year":"1997","journal-title":"J. Organomet. Chem."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"890","DOI":"10.1055\/s-2006-926345","article-title":"Convenient Titration Method for Organometallic Zinc, Magnesium, and Lanthanide Reagents","volume":"2006","author":"Krasovskiy","year":"2006","journal-title":"Synthesis"},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"7300","DOI":"10.1021\/ja00069a032","article-title":"Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PiPr3 or PtBu2Ph): Stereoelectronic control of the stability of molecular H2 transition metal complexes","volume":"115","author":"Albinati","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"4173","DOI":"10.1021\/ja00011a019","article-title":"Assessment of the \"T1 criterion\" for distinguishing between classical and nonclassical transition-metal hydrides: Hydride relaxation rates in tris(triarylphosphine)osmium tetrahydrides and related polyhydrides","volume":"113","author":"Desrosiers","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"6901","DOI":"10.1073\/pnas.0609707104","article-title":"Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules","volume":"104","author":"Kubas","year":"2007","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/j.jorganchem.2013.07.041","article-title":"Activation of dihydrogen and coordination of molecular H2 on transition metals","volume":"751","author":"Kubas","year":"2014","journal-title":"J. Organomet. Chem."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1107\/S2053229614024929","article-title":"PLATON SQUEEZE: A tool for the calculation of the disordered solvent contribution to the calculated structure factors","volume":"71","author":"Spek","year":"2015","journal-title":"Acta Crystallogr. C"},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta. Crystallogr. A"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/6\/2574\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,13]],"date-time":"2023-03-13T08:01:13Z","timestamp":1678694473000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/6\/2574"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,3,12]]},"references-count":78,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2023,3]]}},"alternative-id":["molecules28062574"],"URL":"http:\/\/dx.doi.org\/10.3390\/molecules28062574","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":["Chemistry (miscellaneous)","Analytical Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Molecular Medicine","Drug Discovery","Pharmaceutical Science"],"published":{"date-parts":[[2023,3,12]]}}} |