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{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,1,18]],"date-time":"2024-01-18T11:39:47Z","timestamp":1705577987520},"reference-count":160,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T00:00:00Z","timestamp":1677024000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2023,4,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>This article covers 50\u2005years of coordination chemistry of transition metal complexes and metal\u2010sulfur aggregates involving thiolate\u2010incorporating ligands by reviewing selected examples. The studies in the coordination chemistry of sulfur\u2010rich ligands have been undoubtedly triggered and fed by the concomitant development of bioinorganic chemistry, particularly of iron\u2010sulfur enzymes. The review is broken down in five sections, which examine complexes of increasing nuclearity, including binuclear complexes based on compartmental macrocyclic ligands. We show also how ligand engineering has allowed the researchers in the field to control the nuclearity of the complexes, which was a particularly difficult task for sulfur\u2010based ligands, as thiolates show a strong tendency to coordinate to more than one metal cation at once.<\/jats:p>","DOI":"10.1002\/ejic.202200739","type":"journal-article","created":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T12:21:26Z","timestamp":1677068486000},"update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Fifty Years of Inorganic Biomimetic Chemistry: From the Complexation of Single Metal Cations to Polynuclear Metal Complexes by Multidentate Thiolate Ligands"],"prefix":"10.1002","volume":"26","author":[{"given":"Josef","family":"Taut","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Leipzig Johannisallee 29 04103 Leipzig Germany"},{"name":"Institut de Chimie de Strasbourg UMR 7177 CNRS-Universit\u00e9 de Strasbourg 1, rue Blaise Pascal 67008 Strasbourg France"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-8868-0535","authenticated-orcid":false,"given":"Jean\u2010Claude","family":"Chambron","sequence":"additional","affiliation":[{"name":"Institut de Chimie de Strasbourg UMR 7177 CNRS-Universit\u00e9 de Strasbourg 1, rue Blaise Pascal 67008 Strasbourg France"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-5386-2809","authenticated-orcid":false,"given":"Berthold","family":"Kersting","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Leipzig Johannisallee 29 04103 Leipzig Germany"}]}],"member":"311","published-online":{"date-parts":[[2023,2,22]]},"reference":[{"key":"e_1_2_11_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20451"},{"key":"e_1_2_11_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b300245d"},{"key":"e_1_2_11_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200701108"},{"key":"e_1_2_11_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/CC9960000457"},{"key":"e_1_2_11_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)84307-7"},{"key":"e_1_2_11_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/B303851C"},{"key":"e_1_2_11_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00225B"},{"key":"e_1_2_11_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00300-9"},{"key":"e_1_2_11_9_1","unstructured":"\u00a0"},{"key":"e_1_2_11_10_2","first-page":"435","volume":"4","author":"Isani G.","year":"2014","journal-title":"Biomol. Eng."},{"key":"e_1_2_11_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/iub.1618"},{"key":"e_1_2_11_12_1","unstructured":"\u00a0"},{"key":"e_1_2_11_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/nrm3909"},{"key":"e_1_2_11_14_2","doi-asserted-by